Synthesis and C-C coupling reactivity of a dinuclear Ni(i)-Ni(i) complex supported by a terphenyl diphosphine.

نویسندگان

  • Alexandra Velian
  • Sibo Lin
  • Alexander J M Miller
  • Michael W Day
  • Theodor Agapie
چکیده

Mono- and bimetallic complexes of nickel supported by a terphenyl diphosphine have been synthesized. The reported complexes show diverse metal-arene interactions in the solid state. Reactions of an o,o'-biphenyldiyl dinickel complex with CO and dichloroalkanes lead to fluorene derivatives, indicating the formation of carbon-carbon bonds at a bimetallic moiety.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 132 18  شماره 

صفحات  -

تاریخ انتشار 2010